| 1. Identity statement | ||||
| Reference Type | Journal Article | |||
| Site | mtc-m21b.sid.inpe.br | |||
| Holder Code | isadg {BR SPINPE} ibi 8JMKD3MGPCW/3DT298S | |||
| Identifier | 8JMKD3MGP3W34P/3PUFE65 | |||
| Repository | sid.inpe.br/mtc-m21b/2017/11.07.14.29 (restricted access) | |||
| Last Update | 2017:11.07.14.29.53 (UTC) administrator | |||
| Metadata Repository | sid.inpe.br/mtc-m21b/2017/11.07.14.29.53 | |||
| Metadata Last Update | 2018:06.04.02.27.58 (UTC) administrator | |||
| DOI | 10.1140/epjd/e2017-80103-1 | |||
| ISSN | 1434-6060 | |||
| Citation Key | BarretoEAACGLMP:2017:ImNoVi | |||
| Title | Gas phase Boudouard reactions involving singlet–singlet and singlet–triplet CO vibrationally excited states: implications for the non-equilibrium vibrational kinetics of CO/CO2 plasmas  | |||
| Year | 2017 | |||
| Month | Oct. | |||
| Access Date | 2024, May 15 | |||
| Type of Work | journal article | |||
| Secondary Type | PRE PI | |||
| Number of Files | 1 | |||
| Size | 689 KiB | |||
| 2. Context | ||||
| Author | 1 Barreto, Patrícia Regina Pereira 2 Euclides, Henrique de Oliveira 3 Albernaz, Alessandra F. 4 Aquilanti, Vincenzo 5 Capitelli, Mario 6 Grossi, Gaia 7 Lombardi, Andrea 8 Macheret, Sergey 9 Palazzetti, Federico | |||
| Resume Identifier | 1 8JMKD3MGP5W/3C9JJ2S | |||
| Group | 1 LABAP-COCTE-INPE-MCTIC-GOV-BR 2 CMS-ETES-SESPG-INPE-MCTIC-GOV-BR | |||
| Affiliation | 1 Instituto Nacional de Pesquisas Espaciais (INPE) 2 Instituto Nacional de Pesquisas Espaciais (INPE) 3 Universidade de Brasília (UnB) 4 Università di Perugia 5 NANOTEC – Istituto di Nanotecnologia 6 Università di Perugia 7 Purdue University 8 9 Università di Perugia | |||
| Author e-Mail Address | 1 patricia.barreto@inpe.br | |||
| Journal | European Physical Journal D | |||
| Volume | 71 | |||
| Number | 10 | |||
| Secondary Mark | B1_ENGENHARIAS_IV B1_ENGENHARIAS_III B1_ENGENHARIAS_II B2_MEDICINA_II B2_MATEMÁTICA_/_PROBABILIDADE_E_ESTATÍSTICA B2_ASTRONOMIA_/_FÍSICA B5_MATERIAIS | |||
| History (UTC) | 2017-11-07 14:29:53 :: simone -> administrator :: 2017-11-07 14:29:53 :: administrator -> simone :: 2017 2017-11-07 14:31:25 :: simone -> administrator :: 2017 2017-11-16 01:24:04 :: administrator -> simone :: 2017 2017-12-15 14:05:13 :: simone -> administrator :: 2017 2018-06-04 02:27:58 :: administrator -> simone :: 2017 | |||
| 3. Content and structure | ||||
| Is the master or a copy? | is the master | |||
| Content Stage | completed | |||
| Transferable | 1 | |||
| Content Type | External Contribution | |||
| Version Type | publisher | |||
| Abstract | Rate constants for the Boudouard reactions: CO+ CO -> CO2 + C and CO+ CO -> C2O+ O, involving ground and vibrationally excited states for both singlet-singlet and singlet-triplet reactant CO molecules, have been obtained by using the transition-state theory on an ab initio generated potential energy surface. The dependence of the activation energies for the different processes on the vibrational energy of reactants has been estimated through a parametrization that accounts for the utilization of vibrational energy and is calculated by the forward and backward ab initio activation energies of the relevant processes at zero vibrational energy. The results and their comparison with available experimental reaction rates demonstrate the importance of vibrational excitation not only for the singlet-singlet reactions, but also for the singlet-triplet ones, which are here investigated for the first time. Finally, the implications of the present results on the kinetics of CO/CO2 cold plasmas are discussed: for their modeling the temperature dependence of the obtained rates for singlet-singlet and singlet-triplet reactants in the ground vibrational states have been represented by both Arrhenius and deformed Arrhenius equations. | |||
| Area | FISPLASMA | |||
| Arrangement 1 | urlib.net > BDMCI > Fonds > Produção anterior à 2021 > LABAP > Gas phase Boudouard... | |||
| Arrangement 2 | urlib.net > BDMCI > Fonds > Produção pgr ATUAIS > CMS > Gas phase Boudouard... | |||
| doc Directory Content | access | |||
| source Directory Content | there are no files | |||
| agreement Directory Content |
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| 4. Conditions of access and use | ||||
| Language | en | |||
| Target File | barreto_gas.pdf | |||
| User Group | simone | |||
| Reader Group | administrator simone | |||
| Visibility | shown | |||
| Archiving Policy | denypublisher denyfinaldraft12 | |||
| Read Permission | deny from all and allow from 150.163 | |||
| Update Permission | not transferred | |||
| 5. Allied materials | ||||
| Next Higher Units | 8JMKD3MGPCW/3ET2RFS 8JMKD3MGPCW/3F358GL | |||
| Citing Item List | sid.inpe.br/bibdigital/2013/09.25.21.49 1 sid.inpe.br/mtc-m21/2012/07.13.14.57.42 1 | |||
| Dissemination | WEBSCI; PORTALCAPES; COMPENDEX; SCOPUS. | |||
| Host Collection | sid.inpe.br/mtc-m21b/2013/09.26.14.25.20 | |||
| 6. Notes | ||||
| Empty Fields | alternatejournal archivist callnumber copyholder copyright creatorhistory descriptionlevel e-mailaddress format isbn keywords label lineage mark mirrorrepository nextedition notes orcid pages parameterlist parentrepositories previousedition previouslowerunit progress project rightsholder schedulinginformation secondarydate secondarykey session shorttitle sponsor subject tertiarymark tertiarytype url | |||
| 7. Description control | ||||
| e-Mail (login) | simone | |||
| update | ||||